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Non-destructive Degradation Pattern Decoupling for Ultra-early Battery Prototype Verification Using Physics-informed Machine Learning

1 June 2024
Shengyu Tao
Mengtian Zhang
Zixi Zhao
Haoyang Li
Ruifei Ma
Yu Che
Xin Sun
Lin Su
Xiangyu Chen
Zihao Zhou
Heng Chang
Tingwei Cao
Xiao Xiao
Yaojun Liu
Wenjun Yu
Zhongling Xu
Yang Li
Han Hao
Xuan Zhang
Xiaosong Hu
Guangmin Zhou
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Abstract

Manufacturing complexities and uncertainties have impeded the transition from material prototypes to commercial batteries, making prototype verification critical to quality assessment. A fundamental challenge involves deciphering intertwined chemical processes to characterize degradation patterns and their quantitative relationship with battery performance. Here we show that a physics-informed machine learning approach can quantify and visualize temporally resolved losses concerning thermodynamics and kinetics only using electric signals. Our method enables non-destructive degradation pattern characterization, expediting temperature-adaptable predictions of entire lifetime trajectories, rather than end-of-life points. The verification speed is 25 times faster yet maintaining 95.1% accuracy across temperatures. Such advances facilitate more sustainable management of defective prototypes before massive production, establishing a 19.76 billion USD scrap material recycling market by 2060 in China. By incorporating stepwise charge acceptance as a measure of the initial manufacturing variability of normally identical batteries, we can immediately identify long-term degradation variations. We attribute the predictive power to interpreting machine learning insights using material-agnostic featurization taxonomy for degradation pattern decoupling. Our findings offer new possibilities for dynamic system analysis, such as battery prototype degradation, demonstrating that complex pattern evolutions can be accurately predicted in a non-destructive and data-driven fashion by integrating physics-informed machine learning.

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